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If the student has their log in details for MyWales then they can change the MyWales contact email address via the profile page, this does not change the email address held on the main system, for that to be changed students need to have their respective Institutions request the change.
Go to the following page if you do not have your log in details.
University of Wales University Registry King Edward VII Avenue Cardiff CF10 3NS
Tel: +44 (0)29 2037 6999